대한전기학회:학술대회논문집 (Proceedings of the KIEE Conference)

대한전기학회 (The Korean Institute of Electrical Engineers)
권호 표지

분자집합체의 제조 및 특성연구

Preparation and Characterization of Molecular Assemblies

  • 이해원 (한국화학연구소 무기화학제3연구실) ;
  • 백행남 (한국화학연구소 무기화학제3연구실)
  • Lee, Hai-Won (Korea Research Institute of Chemical Technology, Inorganic Lab 3) ;
  • Paik, Hang-Nam (Korea Research Institute of Chemical Technology, Inorganic Lab 3)
  • 발행 : 1989.11.25
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초록

Multilayer films of inorganic analogues of Langmuir-Blodgett films have been prepared on silicon and gold substrates and characterized by ellipsometry, XPS, FT-IRRS, and electrochemical measurements. The deposition technique requires first covalent attachment or adsorption of a phosphonic acid anchoring agent; $HO(CH_3)(CH_2)_2Si(CH_2)_3PO_3H_2$ and $[-S(CH_2)_4PO_3H_2]_2$ were used with Si and Au, respectively. The functionalized substrates are exposed alternately to aqueous $ZrOCl_2$ and l,l0-decanediylbis(phosphonic acid) solutions to yield multilayer films. Surface-sensitive probes show that the films are compact and grow in an oriented fashion suggestive of good structural order.

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