The Influence of the Degree of Crystallinity and Dielectric Characteristics due to Thermal Aging of Polyprophylene

열처리가 폴리플로필렌의 결정화도와 유전특성에 미치는 영향

This paper was a study on dielectic characteristics of polypropylen film which were annealled in air and qunched in nitorgen after aging for 5[Hr]. Dielectric characteristics of specimen were measured in temperature of the range of 15-120[$^{\circ}C$], and in frequency of the range of $30-1{\times}10^6$[Hz.] As the result, for dielectric relaxation $\beta$-peak was observed in 20[$^{\circ}C$], and $\alpha$-peak was observed in 90[$^{\circ}C$]. Also, it was explained that $\alpha$-peak attributed due to armorphous region and $\beta$-peak attributed due to crystalline region and activation energy from dielectric loss spectra was obtained 34.5[kcal/mole] for $\alpha$-peak and 80.5[Kcal/mole] for $\beta$-peak, respectively.